Chapter 7- Periodicity and Atomic Structure

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Periodic Law

When elements are arranged in order of increasing atomic numbers, elements with similar properties occur at periodic (regular) intervals.

Who proposed Periodic Law?

Dmitri Ivanovich Mendeleev and Julius Lothar Meyer in 1869

effective nuclear charge, Z(eef)

the net nuclear charge that an electron feels from attractions to the protons in the nucleus and repulsions from all the other electrons

Within a particular shell, electrons in subshells with lower values of l "shield" electrons with (higher/lower) values of l more effectively.

higher

Electrons with higher values of l feel (more/less) attraction for the nucleus than do electrons with lower values of l because they are more "shielded" from the nucleus.

less

The more effective the other __________ are at repelling an outer _______, the more shielded we say the ________ is from the nucleus.

electron(s)

In many electron atom, an electron in a ___ orbital is higher in energy than an electron in a 2s orbital.

2p

The order of filling orbitals r______ the extent of the shielding effect of electrons in many electron atoms.

reflects

atomic radius

1/2 the distance between the nuclei of adjacent like atoms in a compound

We find experimentally that the atomic radius of the elements tend to do what as we move down the periodic table.

increase in size

We find experimentally that the atomic radius of the elements tend to do what as we move to the right across the periodic table?

decrease

A shell contains

all the orbitals of an atom that have the same n quantum number

Electron shells are (exact,diffuse) regions of higher electron density.

diffuse

The electron density for electrons with a larger principal quantum number is found (closer,farther)from the nucleus of the atom.

farther

the distance of a shell from the nucleus is explained by the _____ ___ ______.

effective nuclear charge

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