Electrochemistry Test

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hurricane14  on March 16, 2012

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Electrochemistry Test

Oxidation
loss of electrons
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Definitions

Oxidation loss of electrons
Reduction gain of electrons
Oxidizing agent something that is being duced by taking electrons from something else
Reducing agent something that is being oxidized by reducing something else
Oxidation # rules a) elements are zero
b) in componds
i) oxygen is -2 (except in peroxide)
ii) group 1 and group 2 are +1 and +2
iii) Hydrogen is +1 (unless with metals)
Anode (-) where oxidation occurs and where electrons are produced
Cathode (+) where reduction occurs and where electrons are used
Relatively negative Ered means... "likes" to lose electrons (oxidation) -> anode
Relatively positive Ered means... "likes" to gain electrons (reduction) -> cathode
Electrons go from _______ to _______. Electrons go from ANODE to CATHODE.
If you get a negative net Ecell than... the equation is "backwards."
When at equilibrium cells are ______ and voltage is _______. When at equilibrium cells are FLAT and voltage is ZERO.
Ecell = Ecell = E˚cell - 0.0592/n * logQ
E˚cell = RT/nF *lnK
Charge (Q) = Q=It
Faraday's constant = 96,500 C/mols of electrons
ΔG˚= ΔG˚= -nFE˚
ΔG˚= -RTlnK

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