Kinetic Theory, Reaction Rates and Energy Effects

About this set

Created by:

jannika12  on May 22, 2012

Subjects:

Chemistry

Description:

quantitive relationships between gases, colligative properties, vapour pressure and boiling pressure, and energy effects.

Classes:

Kinetic Theory, Equilibrium, Reactions, Energy Effects and Rates

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Kinetic Theory, Reaction Rates and Energy Effects

Boyle's Law (P+V):
Pressure and volume are INVERSELY proportional.
i.e. -as pressure increase, volume decreases.
-as pressure decreases, volume increases.

P1V1 = P2V2
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Definitions

Boyle's Law (P+V): Pressure and volume are INVERSELY proportional.
i.e. -as pressure increase, volume decreases.
-as pressure decreases, volume increases.

P1V1 = P2V2
Charle's Law (V+T): Volume and temp. are DIRECTLY proportional
i.e if temp increases, volume increases & if temp decreases, volume decreases.

V1/T1 = V2/T2
*Use KELVIN (K) rather than celsius.
^0C + 273 = K
K - 273 = ^0C
Combined Gas Law (P,V and T): P1V1/ T1 = P2V2/T2
Colligative Properties: Vapour pressure, melting temperature and boiling temperature.
*Applies to liquids and solutions.
Boiling Pressure: As a liquid boils, bubbles of gas form inside the liquid, and if there's enough pressure inside the bubble, it will rise to the surface, burst and release vapour.
=> When MAX vapour pressure = Atmosphere Pressure
Define: Vapour Pressure Collisions of the vapour from the liquid.
Adding a Solute (Effects on Boiling Point and Melting Point): B.Point and M.Point are changed by adding another chemical;
B.point increases, but freezing point decreases.

The more moles of solute (i.e. greater number of particles attracting H2O), the higher the boiling point (due to increased number of ions).
Energy Effects: -Energy is measured in kJ, and in an equations, kJ/mol.
-Reactants have a given amount of chemical energy/ enthalpy (Hr).
- Products have a given amount of enthalpy (Hp).

=> The amount of energy GIVEN OUT OR ABSORBED is called the HEAT OF THE REACTION.

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