Honors Chemistry Chapter 6 Lecture Notes

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12le  on September 26, 2010

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honors chemistry, chapter 6, sharon

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Honors Chemistry Chapter 6 Lecture Notes Quiz

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Honors Chemistry Chapter 6 Lecture Notes

if s and p sublevels are full
outer level is considered full
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if s and p sublevels are full outer level is considered full
outer level full most stable situation
8 electrons in outer level makes an atom become unreactive
helium exception because it only has one full orbital
if it can't have full outer level, atoms likes to have half filled orbitals these are slightlt more stable (less reactive) than other choices
Cr [Ar] 4s1 3d5
Cu [Ar] s1 3d10
cation positive ion
anion negative ion
why do atoms become ions to become more stable (octet rule)
what does the 1st column do? lose one election
what do metallic elements do when forming ions lose electios
positive ions are smaller then corresponding neutral atoms because it lost one energy level (goes down a shell energy level, decreasing the size) positive char (p) hasnt changed but pulling on fewer electrons
what do halogens do gain 1 electron
nonmentals do what when forming ions gain electrons
negative ions bigger than corresponding neutral atoms because there are more electrons crowding
metal activity inc toward bottom left (Fr)
nonmetal activity inc toward top right but skips noble gases (F)
first ionization energy energy required to remove electrons from gaseous atom
x(g) + E ~> x+(g) + e- (E needed)
units (KJ/mol)
ionzation energy to right increases to right because inc nuclear charge (or more protons)
ionization energy column trend decreases down a column because electron is greater distance from nucleus, valence electrons are shielded from pull of nucleus by core electron
ionization energy exception trend electron from full or 1/2 full sublevel more stable than trend so greater ionization energy
metal ionization energy low 1st IE; takes little E to remove e-
nonmetal ionization energy high 1st IE
electronegativity relative tendency of an atom to attract electrons to itself when it is chemically combined with another element
highest electronegativity Flourine
electronegativity upper right increases to upper right (not noble gases) b/c less distance from nucleus to outer reacting electrons, shielding effect less so it does not affect reacting electron so increases at top of group; more protons in nucleus so more pull for outer electron as go across row to right
electron affinities the energy change that accompanies the addition of an electron to a gaseous atom
x(g) + e- ~> x-(g) + E (usually energy given off)
electron affinity across a period across a period inc to right because increased nuclear char (#p) but if stable will cause deviation
negative electron affinity means more stable as is, does not want more electrons (must add E to force it to take that electron)
metals electron affinity gives off less E so smaller electron affinity some even neg values

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