IB Chem examinable definitions

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slick94  on June 5, 2011

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IB Chem examinable definitions

Bronsted-Lowry Base
Proton/H+ acceptor
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Bronsted-Lowry Base Proton/H+ acceptor
Bronsted-Lowry Acid Proton/H+ donor
Lewis Acid electron pair acceptor
Lewis Base electron pair donor
activation energy, Ea minimum energy required in order for the reactants to collide with sufficient energy to break the bonds in the reactants so the products can form
rate of reaction decrease in the concentration of reactants per unit time or the increase in the concentration of products per unit time.
exothermic reaction the enthalpy of the products is less than that of the reactants, a reaction will lose energy, primarily as heat to its surroundings
endothermic reaction the enthalpy of the products is greater than that of the reactants, a reaction will absorb energy as heat from its surroundings.
standard enthalpy heat energy transferred under standard conditions, pressure 101.3 kPa, temperature 298 K. Only ∆H can be measured, not H for the initial or final state of a system.
Average bond enthalpy The amount of energy required to break one mole of bonds in the gaseous state averaged across a range of compounds containing that bond
electronegativity the ability of an atom to attract a pair of electrons in a bond. increases across a period and down a group.
first ionization energy the minimum energy required to completely remove the first electron from one more of gaseous atoms. involves a transition of an electron from its ground state n=1 energy level to n= infinity.
mass number (A) the total number of protons and neutrons in one atom of an element
atomic number (Z) the number of protons in one atom of an element
isotopes of an element atoms of the same element with a different amount of neutrons and subsequently different masses. they have the same chemical properties but different physical properties
continuous spectrum has all seven frequencies of light. ex. a rainbow
line spectrum shows the colors shown as a result of energy being released from an atom after it is excited
relative atomic mass (Ar) the weighted mean mass of the masses of the naturally occurring isotopes of an element relative to one atom of 12-C
relative molecular mass (Mr) the average mass of a molecule compared to one atom of 12-C
empirical formula The simplest whole number ratio of the atoms of each element in a compound.
molecular formula The integer multiple of the empirical formula. E.g. if the empirical formula is CH the molecular formula could be C2H2.
solute substance being dissolved
solvent the substance that the solute is dissolved in
solution Homogenous mixture of two or more substances; a solute and solvent.
concentration The amount/moles of substance contained within a given volume of solution. Symbol c or [ ].
covalent bond the electrostatic attraction between a pair of electrons and positively charge nuclei. Formed as a result of electron sharing.
giant structures refers to covalent, ionic and metallic structures where the exact number or moles of atoms is not definite. Also called a network, crystalline or lattice structure.
characteristics of giant structures strong intramolecular forces between the particles and weak or no intermolecular forces.
hydrogen bonding strongest type of intermolecular force formed between polar covalent molecules that contain covalent bonds where hydrogen is bonded to fluorine (H-F), hydrogen is attached to nitrogen (H-N) and hydrogen is attached to oxygen (H-O).
ionic bond an electrostatic attraction or force between oppositely charged ions
Metallic bonding electrostatic attraction between a lattice of positive ions and delocalized electrons
malleable when a substance can be beaten or bent into shape without breaking.
permanent dipole forces medium strength intermolecular forces formed between polar covalent molecules.
Van der Waals forces very weak temporarily induced dipole intermolecular forces formed between non-polar covalent molecules.
allotrope atoms arranged in different ways, giving rise to different forms of the element. For example carbon atoms can be arranged in three different ways giving rise to diamonds, graphite and fullerenes.

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