TPR MCAT Orgo Chapter 3 vocab

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patwu89  on July 15, 2011

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TPR MCAT Orgo Chapter 3 vocab

Constitutional Isomers
Different bond connectivity
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Definitions

Constitutional Isomers Different bond connectivity
Isomers same molecular formula, different structures
Conformational Isomers Differ by rotation around a sigma bond
Stereoisomers Same bond connectivity, different spatial arrangement of atoms
Enantiomers Non-idential mirror images (chiral molecules)
Meso Contains chiral centers and an internal plane of symmetry (achiral molecule)
Diastereomers Stereoisomers that are not enantiomers
Geometric isomers Diastereomers that differ in orientation of substituents around a ring or double bond
Epimers Diastereomers that differ in absolute configuration at only one chiral center
Anomers Epimers that form as a result of ring closure

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