Quantum Theory

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dhanushyab  on September 26, 2011

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chemistry

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Quantum Theory

Democritus
First coined the term 'atoms'
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Democritus First coined the term 'atoms'
Einstein Explained the "photoelectric effect" by proposing that light is both a wave and a particle
Planck proposed that atoms accept ONLY specific amounts of energy called quanta
Dalton proposed that all matter is made up of atoms and established ideas about how atoms combine to form compounds in definite proportions.
Bohr proposed that electrons orbit the nucleus in circular orbits (solar system model)
Thomson positive and negative charges make up his plum pudding model.
Millikan determined the mass to charge ratio of an electron
Rutherford discovered the nucleus
Photoelectric Effect uses stopping voltage to determine the energy of electrons, and enabled Planck's constant to directly relate frequency to energy.
increases As energy increases, frequency______?
Red Which has lower energy? Red of Violet?
Wavelength Distance between corresponding points on adjacent waves. Length of one complete wave.
Frequency number of waves that pass a point during a certain time period. Defined as the number of waves that pass a given point in a specific time (1 second)
Amplitude distance from the origin to the trough or crest.
Quanta energy that is emitted in small specific amounts.
Photoelectric Effect the emission of electrons from a metal when light shines on a metal.
Frequency+wavelength formula C=λv
Inversely Frequency+wavelength are_____proportional.
Higher Low energy waves have _____ frequencies.
Length of visible spectrum 400nm-700nm
Violet Which has higher energy? Red or Violet?
Photon bundles of light energy that is emitted by electrons as they go from higher energy levels to lower energy levels. Particle of electromagnetic radiation having zero mass and carrying a quantum of energy.
Each element has a unique bright-line emission spectrum What is the significance of the Line Emission Spectrum?
Proportional Energy of a photon is ______ to its frequency.
Energy+Frequency Formula E=hv
Energy+wavelength Formula E=hc/λ
Hertz (Hz) what is frequency measured in?
Joules (J) what is energy measured in?
meters, nm, etc what is wavelength measured in?
Planck's constant 6.6262*10^34 J.s
C=speed of light 3.00*10^8
Orbital region in space where there is 90% probability of finding an electron. "electron cloud"
Two Each orbital can hold___electrons
Two The S sublevel has____electrons
One The S sublevel has___orbitals
Three The P sublevel has______orbitals
Six The P sublevel has_____electrons
Five The D sublevel has____orbitals
Ten The D sublevel has____electrons
Photon When the electrons falls to a lower energy level, a _____ is emitted.
Size of the orbital What does the energy level tell you?
Aufbau Principle electrons fill the lowest energy orbitals first. An electron occupies the lowest-energy orbital that can receive it.
Pauli's Exclusion Principle Each orbital can hold TWO electrons, but they must have opposite spins.
Hund's Rule Within a sublevel,place one electron per orbital before pairing them up. "urinal analogy"
Ground State lowest energy state of an atom
Excited State a state in which an atom has a higher potential energy that it has in its ground state.
Principle quantum number symbolized by n, indicates the main energy level occupied by the electron.
Angular momentum number symbolized by l, indicates the shape of the orbital
s-spherical
p-dumbbell
Magnetic quantum number symbolized by m, indicates the orientation of an orbital around the nucleus.
Spin quantum number has only two possible values (+1/2, or -1/2) which indicate the two fundamental spin states of an electron in an orbital
Higher As the wavelenght become shorter, the energy is______.
Bohr Model electrons orbit the nucleus in circular paths of fixed energy.
Quantum Numbers specify the "address" of each electron in an atom
S-orbitals electrons are found within a sphere around the nucleus
D-orbitals most appear to be the combination of two p-orbitals, "daisy"
P-orbital orbital that look like "dumbbells or propellers" or tear drops.
F-orbitals really complicating structure.
n # of sublevels per level
n^2 # of orbitals per level
Dalton All atoms of the same element are identical, other atoms are different. Proposed that atoms are small, uniformely dense, and indivisible.
Crooke & Thomson used a cathode ray tube. Determined that atoms also contain witin themselves small negatively charged particles. They discovered the electron, the 'first' subatomic particle.
Rutherford He tested Thomson's model with the gold foil experiment. According to Thomson's model, radiation particles should not be deflected. but in his experiment, some radiation was deflected.
Chadwick Discovered the neutron. He reevaluates data and proposes that the radiation was actually a "massive" particle.
Planck will only accept energy in small 'quantized' packets.
Broglie Applied wave-particle theory to electrons. Found that electrons exhibit wave properties.
Schrodinger The wavefunction helps describes the location of the electron, and its probable location. Electrons have a wavelenght.
Ion electron configuration write the electron configuration for the closest Noble Gas
Ion formation Atoms gain or lose electrons to become more stable.
Heisenberg Uncertainty Principle impossible to know both the velocity and position of an electron at the same time.
Pauli Exclusion Principle no to electrons in an atom can have the same 4 quantum numbers.

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