Chapter 2 The molecular Basis of Life

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Created by:

alicekennedy11  on October 3, 2011

Subjects:

molecules & cells

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Chapter 2 The molecular Basis of Life

every factor of 2 difference in [H+] = how many pH units?
.3
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every factor of 2 difference in [H+] = how many pH units? .3
when diluting a stock solution the amount of stock solution you should use = [what you want]/[what you need]*final volume
methods of finding pH pH meter, pH paper, titrate solution
CO2 + H2O yields H2CO3, weak acid
Keq = [H+][A-]/[HA]
buffer a solution of a weak acid and its conjugate base that resist changes in pH in both directions. buffer works best in the middle of its range where the amount of undissasociated acid is about equal to the amount of conjugate base.
ionization of water very small: 10^-7 (pH=7)
water is the best solvent why? -polarity, hydrogen bonding, small size, bent shape
why does surface tension occur? meniscus forms with cohesion: water molecules at the surface hydrogen bond with those below them they create a net downward pull. adhesion:water molecules adhere to the glass and resist the downward pull.
why is water denser as a liquid than a solid? ice- hydrogen bonds form a crystal structure with lots of spaces
how did life first begin, without a foundation? -hot and molten earth, volcanoes released CO2, N2, and H2O vapor, H2O cools and forms oceans, reactions can occur in solution
theory of chemical evolution simple chemical compounds in the ancient atmosphere and ocean combined to form more complex substances found in living cells using energy from heat + sunlight
1st law of thermodynamics energy is conserved
exergonic reactants loose potential energy
delta G = delta H -T*delta S
energy started chemical evolution by the formation of free radicals
free radicals are highly reactive atoms with an unpaired electron broken off by photons
number of collisions depends on temperature + concentration of reactants
the formation of H2CO (formaldehyde) +HCN was a critical step in chemical evolution because energy from sunlight was converted to chemical energy (PE in chemical bonds)
functional groups amino, carbonyl, carboxyl, hydroxyl, sulfyhydryl, phosphate

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