Rules for Determining the Oxidation State (Number)

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Created by:

annehaskins  on October 12, 2011

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Rules for Determining the Oxidation State (Number)

Element
The oxidation state (number) of atom in an element is ALWAYS zero
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Element The oxidation state (number) of atom in an element is ALWAYS zero
Monoatomic Ions The oxidation state (number) of an atom in a monatomic ion EQUALS the charge on the ion
Oxygen The oxidation state (number) of oxygen is -2 in MOST compounds (Exceptions: Hydrogen Peroxide H2O2 and other peroxides, where it is -1)
Hydrogen The oxidation state (number) of hydrogen is +1 in MOST of its compounds (Exceptions: Metal Hydrides, such as NaH or CaH2, where it is -1)
Halogens The oxidation state (number) of fluorine is -1 in ALL compounds. Each of the other halogens (Cl, Br and I) has an oxidation number of -1 in binary compounds, except when the other element is a halogen above in the periodic table or oxygen.
Compounds and Ions The sum of the oxidation states (numbers) of the atoms in a compound is ZERO. The sum of the oxidation numbers of atoms in a polyatomic ion EQUALS the charge on the ion.

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