GC2 Test 4

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Created by:

Hinagikun  on October 31, 2011

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general chemistry 2

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GC2 Test 4

Arrehinus definition of an acid
an acid is a substance that produces H+/H3O+ (hydrogen/hydromium ion) when placed in water, a process called ionization
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Terms

Definitions

Arrehinus definition of an acid an acid is a substance that produces H+/H3O+ (hydrogen/hydromium ion) when placed in water, a process called ionization
According to the Arrehinus concept, a strong acid... and a weak acid.... ionizes to an extent of 100%
ionizes to an extent of less than 100%
Examples of Arrehinus acids include... HCl, HBr, HI, HC2H3O2, etc.
Arrehinus definition of a base a base is a substance that produces OH- (hydroxide ions) when placed in water
According to the Arrehinus concept, a strong base... produces OH- ions to 100%
Bronsted/Lowry definition of an acid an acid is a substance that can donate a proton
Bronsted/Lowry definition of a base a base is a substance that can accept a proton
According to the Bronsted/Lowry concept, a strong acid... and a weak acid... has a large tendency to donate H+
has a small tendency to donate H+
According to the Bronsted/Lowry concept, a strong base... and a weak base... has a large tendency to accept H+
has a small tendency to accept H+
Strong acids have... weak conjugate bases
Weak acids have... strong conjugate bases
Strong bases have... weak conjugate acids
Weak bases have... strong conjugate acids
H2O is amphiprotic, which means... it can act as either an acid or a base depending on what it's with
Water is the conjugate base of... H3O+, hydromium ion
Water is the conjugate acid of... OH-, hydroxide ion
Examples of Bronsted/Lowry acids include... HF, H3O+, NH4+, H2O
Examples of Arrehinus bases include... NaOH, KOH, Ca(OH)2, Ba(OH)2
Examples of Bronsted/Lowry acids include... F-, H2O, NH3, OH-
Lewis definition of an acid... a molecule or ion that can accept an electron pair (electrophile: seeks electrons), has an atom in it with an empty orbital
Lewis definition of a base... a molecule or ion that has an inshared pair of electrons on an atom (nucleophile: seeks a nucleus to bond with)
Acid/Base reaction according to the Lewis concept... Base (donates e-) + Acid (accept e-) --> Product (new single covalent bond from the shared e-)
K[H2O] = ... [H+][OH-] = 1 x 10^-14
pH + pOH = ... 14
pH = ... -log[H+]
pOH = ... -log[OH-]
[H+] = ... 10^-pH
[OH-] = ... 10^-pOH
Method 1 to find concentration of either [H+] or [OH-]... [H+] = 10^-pH
[OH-] 10^-pOH
Method 2 to find concentration of either [H+] or [OH-] (teacher's method)... [H+] = 1*10^-4 / [OH-]
[OH-] = 1*10^-4 / [H+]
Checking RA, method 1... show that [HA]0 - x = [HA]0
Checking RA, method 2... 2% rule, y = 0.2[HA]0
If x < y, RA is valid
For weak acids, as [HA]0 decreases... %I increases
The strong acids include... HCl, HNO3, H2SO4, HBr, HI, HClO4
If [H3O+] = 1...
If [H3O+] > 1...
pH = 0
pH < 0

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