| Term | Definition |
|
chemical reaction |
change from reactants to products; rearrangement of bonds between atoms |
|
mixture |
blend of 2 or more substances |
|
homogeneous mixture |
uniform composition; same throughout; "one phase" |
|
heterogeneous |
not uniform composition; 2 or more phases |
|
element |
simplest form of matter |
|
law of conservation of mass |
matter cannot be created nor destroyed (it can be rearranged to form new bonds) |
|
observation |
observe with senses |
|
interpretation |
judgment about an observation |
|
compound |
2 or more elements chemically combined that can only be separated with a chemical reaction |
|
error |
accepted value - experimental value |
|
percent error |
(absolute value of error/accepted value) x 100% |
|
accuracy |
how close a measurement is to the "true" value |
|
precision |
how close a set of measurements is to each other |
|
density |
mass/volume |
|
specific gravity |
compares density of substance to density of a reference substance |
|
density of water |
1g or 1 mL |
|
absolute zero |
0 K, or -273 degrees celcius; all molecular motion stops |
|
mole |
6.02 x 10^23 representative particles/mole |
|
molar mass |
the mass of one mole of any substance; atomic mass in grams |
|
22.4 L |
1 mole of any gas at STP |
|
standard temperature and pressure |
STP |
|
percent mass |
(mass of element in compound/molar mass of compound) x 100% |
|
empirical formula |
lower whole number ratio of atoms of the elements in a compound |
|
molecular formula |
"real" formula; same as or some whole number multiple of the empirical formula |
|
OKAY! |
KNOW HOW TO CALCULATE EMPIRICAL/MOLECULAR FORMULA. OKAY?! |
|
combination reaction |
2 things combine to form 1 thing |
|
decomposition reaction |
1 thing turns into 2 things |
|
single replacement reaction |
element + compound turns into new compound + element |
|
double replacement reaction |
rxn where given 2 compounds, cations trade places |
|
combustion reaction |
rxn that involves burning something in oxygen |
|
hydrocarbon |
CHO |
|
isotope |
atoms with differing numbers of neutrons; differing masses |
|
alpha particle |
helium particle; decreases atomic number by 2, mass by 4, neutrons by 2 |
|
beta particle |
converts neutrons into protons; increases atomic number by 1; no mass; decreases neutrons by 1 |
|
positron |
converts protons into neutrons; decreases atomic number by 1; no mass; increases number of neutrons by 1 |
|
gamma radiation |
usually emitted w/ alpha + beta particles; electromagnetic radiation; no mass, no charge=no change in mass when emitted |
|
alpha emission |
radiation: cannot penetrate dead skin, paper; can penetrate soft tissue |
|
beta emission |
radiation: can be stopped by wood/aluminum foil |
|
gamma emission |
radiation: can be stopped by several inches of Pb or concrete |
|
half-life |
amount of time it takes for half the atoms of a radioactive isotope to decay to products |
|
carbon dating |
determining the age of objects using the ratio of C-12 to C-14 |
|
transmutation |
the conversion of one element into another |
|
transuranium elements |
elements with atomic numbers greater than 92; manmade; radioactive |
|
fission reaction |
the splitting of a nucleus |
|
number of molecules; number of moles |
what coefficients in chem rxns represent |
|
limiting reactant |
reactant that runs out (determines amount of product formed) |
|
excess reactant |
the reactant that is left over |
|
percent yield |
(actual yield/theoretical yield) x 100% |
|
kinetic theory |
theory: particles in all states of matter are in constant motion |
|
kinetic energy |
energy of motion |
|
potential energy |
stored energy (chemical energy) |
|
elastic collision |
energy is transferred totally from one particle to another |
|
gas pressure |
the force exerted by gas particles (in motion) hitting a body |
|
pressure |
force/area |
|
vacuum |
no particles (air) --> no force --> no pressure |
|
atmospheric pressure |
pressure caused by gas particles in air/atmosphere |
|
barometer |
measures atmospheric air pressure |
|
760 mm Hg; 101.3 kPa |
1 atmosphere |
|
1/2 mv^2 |
kinetic energy formula |
|
evaporation |
a cooling process; molecules at a higher temperature leave to become gas, cooler particles left over |
|
perspiration |
sweating |
|
vapor pressure |
pressure due to the gas above the liquid |
|
boiling point |
when vapor pressure = atmospheric pressure |
|
melting point |
temp at which a solid melts and becomes a liquid |
|
unit cell |
smallest group of particles within a crystal which retains the geometric shape of the crystal |
|
allotrope |
different molecular forms of the same element in the same physical state |
|
amorphous solids |
solids which lack an ordered internal structure (rubber, glass) |
|
crystalline solid |
have orderly arrangement of atoms, ions, molecules that make up the solid |
|
critical point |
liquid and gas indistinguishable (super critical fluid) |
|
triple point |
where all three phases coexist |
|
thermochemistry |
the study of heat changes that occur during a reaction |
|
energy |
the capacity to do work or the ability to supply heat |
|
heat |
energy that is transferred from one substance to another due to temperature differences; can't measure it directly (only its effects) |
|
thermoequilibrium |
heat stops moving; heat moves from hot to cold until the temps are equal |
|
positive q value |
heat flows into system; heat is absorbed; "endothermic"; takes in heat; feels cold |
|
negative q value |
heat flowing out of system; heat released; "exothermic"; feels warm |
|
law of conservation of energy |
energy cannot be created nor destroyed |
|
Calorie |
amount of energy required to raise 1g water 1degree Celcius |
|
specific heat |
amount of energy required to raise 1g of a SUBSTANCE 1 degree celcius |
|
Q = CMAT |
Q=CMAT |
|
heat capacity |
amount of energy (heat) required to raise temp of a specific OBJECT |
|
specific heat x mass of a substance |
equation for heat capacity |
|
hess' law |
if 2 or more chemical rxns combine to give a final equation then you can add the deltaH values to get the final deltaH |
|
democritus |
coined "atom" |
|
dalton's atomic theory |
all elements composed of atoms; diff properties of diff elements can be explained by fact that diff atoms are fundamentally diff; each element made from 1 kind of atom; atoms of diff elements combine in whole number ratios to form compounds; chem rxns change how atoms bonded to each other |
|
atom |
smallest particle of an element that retains properties of that element |
|
jj thomson |
discovered electron; cathode ray tube; plum pudding model |
|
millikan |
oil drop experiment: determined exact charge of electron; found mass of electron = 1/1840 mass of H atom |
|
golstein |
discovered proton |
|
chadwick |
discovered neutron |
|
1 |
mass of proton; mass of neutron |
|
rutherford |
discovered nucleus; bombarded gold foil with pos alpha particles |
|
(% abundance) x (mass of 1 isotope) + (% abundance) x (mass of 1 isotope) |
average atomic mass |
|
dmitri mendeleev |
developed periodic table (arranged elements by mass, similar properties) |
|
mosely |
arranged elements by atomic number |
|
periodic law |
certain properties of elements repeat periodically when arranged by atomic number |
|
neils bohr |
planetary model: electrons move in fixed paths aroun nucleus, have fixed energy |
|
schrodinger |
wrote mathematical equation for location of electron; based on probability |
|
energy levels |
areas around nucleus where electrons most likely to be found |
|
aufbau principle |
electron enters orbitals with lower energy first |
|
pauli exclusion principle |
orbitals may hold at most two electrons; must have opposite spins |
|
hund's rule |
electrons going into orbitals w/ same energy fill one electron per orbital all with same spins |
|
isoelectronic |
having the same electron configuration |
|
electromagnetic radiation |
energy; travels in waves; visible light is a small section of spectrum |
|
lambda |
symbol for wavelength |
|
nu |
symbol for frequency |
|
3.0 x 10^8 m/s |
speed of light = c = speed of electromagnetic radiation in a vacuum |
|
planck |
scientist who related energy of a wave to its frequency |
|
E = h x nu |
planck's constant where h = 6.62 x 10^-34 |
|
photon |
light quanta |
|
photoelectric effect |
shine light on metal to observe effects |
|
frequency |
color |
|
amplitude |
brightness |
|
lambda = h/mv |
debroglie equation |
|
heisenberg uncertainty principle |
can't know an object's position and motion at the same time |
|
shielding effect |
electrons closer to nucleus shield outer electrons from nuclear pull |
|
molecular compound |
electrons shared; 2 non-metals; low melting/boiling points; liquid or gas at room temp |
|
ionic compound |
electrostatic attraction; metal + nonmetal; high melting/boiling points; crystalline solids at room temp |
|
binary compound |
compound ending in -ide; only has 2 elements in it |
|
polyatomic ions |
tightly bound groups of atoms that behave as a unit and carry a charge |
|
representative unit |
formula unit (like a "molecule) |
|
metallic bond |
attraction of valence electron for positively charge metal ion; bond b/t 2 metals |
|
alloy |
mixture of 2 or more elements, one of which is a metal |