| Term | Definition |
|
atomic theory |
the theory that all matter is composed of indivisble particles called atoms |
|
law of definite proportions |
any sample of a compound always has the same compostition |
|
law of multiple proportions |
the mass ratio for one of the elements in a compound that combines with a fixed mass of another element can be expressed in small whole numbers |
|
atomic mass |
the mass of an atom in atomic mass units |
|
mole |
the SI unit for measuring the amount of a substance |
|
Avogadro's constant |
the number of particles in 1 mol, 6.00221367*10^23/mol |
|
Carbon-12 |
atom used as standard for atomic mass scale (1 amu= 1/12 the mass of...) |
|
no |
does every atom of an element have the exact same mass? |
|
False |
True or False: Einstein's equation of E=mc^2 disproves the law of conservation of mass |
|
anode |
an electrode through which electrons enter a metal |
|
cathode |
an electrode through which electrons leave a metal |
|
electron |
small negatively charged particle found in atoms |
|
alpha particle |
a positively charged particle produced by some nuclear disintegrations |
|
nucleus |
the central region of an atom made up of protons and neutrons |
|
proton |
a particle with a positive charge found in atomic nuclei |
|
neutron |
a particle with no electric charge found in atomic nuclei |
|
atomic number |
(what number?) the number of protons in the nucleus of an atom |
|
mass number |
the total number of protons and neutrons in the nucleus of an atom equals the... |
|
Coulomb's law |
(whose law?) the force between two charged particles is inversely proportional to the square of the distance between them |
|
isotope |
one of two or more atoms of the same element w/ different numbers of neutrons |
|
radioisotope |
an unstable atom that undergoes radioactive decay |
|
coulombs |
SI unit for electric charge |
|
electrons |
cathode rays are made of... |
|
true (but it's soooo small that it doesn't matter when calculating atomic mass) |
true/false electrons have mass |
|
they originated at the negatively charged cathode |
why did scientists reason that the particles in a cathode ray had a negative charge |
|
yes |
does every atom contain electrons |
|
Rutherford |
_____________ discovered that atoms had a massive, positively charged nucleus and were mostly empty space in his gold foil experiment. |
|
neutrons |
Irene Joliot-Curie and James Chadwick proved the existence of... |
|
number of neutrons |
mass number - atomic number = |
|
the number of electrons |
the number of protons in an atom must equal... |
|
the atomic number |
when expressing an atomic structure in a symbol, this is always to the lower left of the element's symbol |
|
(the) mass number |
when expressing an atomic structure in a symbol, this is always to the upper left of the element's symbol |
|
strong |
the ______ force allows protons and neutrons to form a stable nucleus despite the repulsive force between protons |
|
observations of electrical experiments like the cathode ray experiment |
this led scientists to propose the existence of subatomic particles |
|
Rutherford's gold foil experiment (shot a-particles at gold foil, most went through empty space but some bounced off/ were repelled by positively charged nucleus) |
what showed atoms are mostly empty space and have a positively charged nucleus |
|
isotopes |
______ of the same element are different in stability, properties, number of neutrons |
|
electromagnetic spectrum |
the total range of electromagnetic radiation, ranging from the longest radio waves to the shortest gamma waves |
|
line-emission spectrum |
distinct lines of colored light that are produced when the light produced by excited atoms of an element is passed through a prism |
|
ground state |
the lowest energy state of a quantized system |
|
excited state |
the condition of an atom in a higher energy state than ground state |
|
quantum number |
a number with certain definite values |
|
orbital |
a region of an atom in which there is a high probability of finding one or more electrons |
|
Pauli exclusion principle |
(What principle?) a maximum of two electrons can occupy each orbital, and these electrons must have different spin quantum numbers |
|
electron configuration |
a description of the occupied electron orbitals in an atom |
|
aufbau principle |
(what principle?) electrons in an atom will occupy the lowest energy orbitals available |
|
Hund's rule |
the most stable arrangement of electrons is that with the maximum number of unpaired electrons, all with the same spin quantum number |
|
electrons |
the most important part of an atom in chemistry becausue they occupy most of an atoms volume and determine virtually all of its chemistry |
|
studying the light they emit |
how we gain much of our knowledge of electrons |
|
as frequency increases |
wavelength decreases |
|
red light |
low frequency, long wavelength |
|
violet (light) |
(what color light has) high frequency, short wavelength |
|
frequency |
number of waves that pass a stationary point in one second |
|
wavelength |
distance between two consecutive peaks or troughs of a wave |
|
wavelength |
property of a wave that is measured in meters |
|
frequency |
property of a wave that is measured in hertz |
|
speed of light |
frequency*wavelength= |
|
speed, wavelength, and frequency |
three characteristics by which waves can be described |
|
light |
an electromagnetic wave |
|
false |
(t/f) the Rutherford model of the atom could explain line-emission spectra |
|
lavender glow |
excited hydrogen atoms emit a --- |
|
colors of light (that produce a distinctive line-emission spectrum for that element) |
experiments with elements in the gas phase showed that each element emits characteristic... |
|
Bohr |
_____ showed that excited atoms emit light |
|
an excited electron falls to its ground state |
light is emitted when... |
|
line-emission spectra |
(what does this produce?) emission of characteristic frequencies of light... |
|
400 nm-700nm (violet-red) |
visible spectrum |
|
n, l, m |
unique set of quantum numbers each electron in an atom is assigned |
|
false |
(t/f) every series of three quantum numbers is acceptable |
|
n |
symbol for principal quantum number (shell) , can take whole # values, in practice, values greater than 7 not encountered |
|
n |
the farther the orbital from the nucleus, the larger this quantum number is |
|
electrons orbit like planets |
Rutherford's model |
|
l |
can take any whole # value from 0 to n-1 |
|
m |
may take whole # values depending on l. for example, if l =1 this equals=any from -1 - 1 |
|
false |
more than 2 elecrtons can occupy an orbital (t/f) |
|
m(subscript)s |
symbol (letter) representing spin in a set of quantum numbers |
|
direction of spin |
spin quantum number describes an electrons... |
|
2 possible spin quantum numbers |
-1/2, +1/2 |
|
opposite directions |
two electrons in the same orbitals spin in... |
|
true |
electrons occupy low energy orbitals first (t/f) |
|
s |
_ orbital can hold 2 electrons |
|
p |
_ orbital can hold 6 electrons |
|
10 electrons |
d orbital can hold |
|
f orbital can hold |
14 electrons |
|
asterisk |
when referring to elements an ________indicates excited state |
|
definite proportions, conservation of mass, multiple proportions |
laws that support existence of atoms |
|
mass of carbon-12 |
12 amu (exactly) |
|
1 amu |
mass of what ? 1.6605*10^-27 kg |
|
Avogadro's constant |
Whose constant? 6.022*10^23/mol, number of particles in a mol |
|
protium |
consists solely of 1 electron and 1 proton |
|
true |
isotopes are atoms that have the same atomic number but different mass numbers (t/f) |
|
true |
(t/f) the electromagnetic spectrum includes the wavelengths of radiation of visible light |
|
l |
symbol (letter) for quantum number for subshells, describes shape of orbital |
|
0,1,2 |
when describing the quantum number of a subshell of a atom s, p, d equal what numbers (consecutively) |
|
m(subscript)l |
quantum symbol (letter) for the orbital of an atom, where it is in the subshell |
|
Dalton |
who came up w/ law or multiple proportions? |
|
5 (ml=-2,-1,0,1,2) |
number of orbitals 2 subshell has |
|
quantum numbers |
the 'address' of an electron |
|
Pauli Exclusion Principle |
This means that no 2 electrons have the same set of quantum numbers |
|
paramagnetic |
elements that do not have all of their electrons spin paired, are strongly affected by magnetic fields |
|
diamagnetic |
elements that have all their electrons spin paired and aren't strongly affected by magnetic fields |
|
1s2, 2s2, 2p6, 3s2, 3p6, 4s2, 3d10, 4p6, 5s2, 4d10 |
electron configuration of Iron (atomic # 26) |
|
false |
(t/f) most elements are diamagnetic |
|
true |
(t/f) Helium is diamagnetic |
|
dumbbell |
the p orbital is shaped like this piece of workout equipment... |
|
different spins |
what allows electrons to coexist closely? |
|
2 |
what is the mass ratio of CO? (know how to make law of multiple proportions table) |
|
radiate energy |
according to Bohr's theory an excited atom would... |
|
frequency |
the energy of a photon (quantum) is related to its... |
|
8 |
number of electrons in highest energy level of an argon atom (#18)... |
|
3 |
this (n) main energy level can hold 18 electrons |
|
de Broglie |
his hypothesis means that electrons are like waves confined to the orbit of an atom |
|
Bohr |
he thought electrons orbiting the nucleus were like planets orbiting the sun |
|
false |
(t/f) Dalton's atomic theory said the number of protons equals an atom's atomic number |
|
Millikan |
he calculated the charge on an electron by examining the behavior of charged oil drops in a electric field |
|
Planck |
who figured out that electron magnetic energy is quantized for a given frequency of radiation (or light) |
|
true |
(t/f) energy changes occur in small, specific steps |
|
potential |
electrons farther away from the nucleus of an atom have more ___ energy |
|
false (Mendeleev and Meyer independantly proposed early versions of the periodic table) |
(t/f) Dalton developed the periodic table |
| Add or remove terms from this set |