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Alkene Reactions

Terms in this set (10)

Hydrohalegenation
-HX: X= Cl, Br, I
Int: Carbocation-> can rearrange
Stereoselectivity: stereorandom (none)
Regioselectivty: Markovnikov
Funcitonal group of products: alkyl-halide
Hydrohalegenation with peroxide
-HBR/ROOR
- Int: Radical-> can't rearrange
- Stereoselectivity: stereorandom
-Regioselectivity: Anti-markovnikov
- Functional group of products: alkyl-halides
Catalyzed Hydration
- H2SO4/H2O
- Int: carbocation-> can rearrange
- Stereoselectivity: stereorandom(none)
- Regioselectivity: Markovnikov
Functional Group produced: alcohol
Oxymercuration
- 1.Hg(OAc)2, ROH 2. Na BH4
Int:
Stereoselectivity:
Regioselectivity:
Functional group of product:
Hydroboration
1. BH3 2. H2O2, NaOH, H2)
Int: None-> can't rearrange
Stereoselectivity: syn
Regioselectivity: anti markovnikov
Functional group of product: alcohol
Hydration Oxidation
Br2/CH2Cl
Int: Bridges-> can't rearrange
Stereoselectivity: anti
Regioselectivity: n/a
Functional group of product: dibromo halide
Halogenation
Br2/H2o
Int: Bridges-> can't rearrange
Stereoselectivity: anti
Regioselectivity: n/a
Functional group of product: halohydrin
Halohydrin formation
OsO4
Int:Bridges-> can't rearrange
Stereoselectivity: syn
Regioselectivity: n/a
Functional group of product: syn-diol
Hydrogenation
H2/Pd-c
Int: None- can't rearrange
Stereoselectivity: syn
Regioselectivity: N/A
Functional group of product: alkene->alkane
Ozonolysis
O3
Int: bridged-> can't rearrange
Stereoselectivity: N/A
Regioselectivity: N/A
Functional group of product: ketone, aldehyde, carboxylic acid
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