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Calculate the molar volume of ethane at and and at and , using the van der Waals equation. The van der Waals constants are given in Table 5.7. To simplify, note that the term is small compared with . Hence, it may be approximated with negligible error by substituting from the ideal gas law for in this term. Then the van der Waals equation can be solved for the volume. Compare the results with the values predicted by the ideal gas law.
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