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A coal from Texas which has an ultimate analysis (by mass) of 39.25 percent C, 6.93 percent 41.11 percent 0.72 percent 0.79 percent S, and 11.20 percent ash (non-combustibles) is burned steadily with 40 percent excess air in a power plant boiler. The coal and air enter this boiler at standard conditions, and the products of combustion in the smokestack are at Calculate the heat transfer, in kJ/kg fuel, in this boiler. Include the effect of the sulfur in the energy analysis by noting that sulfur dioxide has an enthalpy of formation of -297,100 kJ/kmol and an average specific heat at constant pressure of
Solution
VerifiedFirst the mole numbers of the components of the coal are determined from their masses:
The total number of moles is . The mole fractions are then:
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