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(a) Data on a single crystal of MnF2\mathrm{MnF}_{2} give χm=0.1463cm3mol1\chi_{m}=0.1463 \mathrm{cm}^{3} \mathrm{mol}^{-1} al 294.53 K. Identify the effective number of unpaired electrons in this compound and compare your result with the theoretical value. (b) Data on a single crystal of NiSO47H2O\mathrm{NiSO}_{4} \cdot 7 \mathrm{H}_{2} \mathrm{O} give χm=6.00×104m3mol1\chi_{\mathrm{m}}=6.00 \times 10^{-4} \mathrm{m}^{3} \mathrm{mol}^{-1} at 298 K. Identify the effective number of unpaired electrons in this compound and compare your result with the theoretical value.

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E15F3

The magnetic susceptibility being proportional to m23kT\dfrac{m^2}{3kT} is a result of the contribution of the thermal averaging of the permanent magnetic moments in the presence of an applied magnetic field. Thus, the spin contribution to the molar magnetic susceptibility is

χm=NAge2μ0μB2S(S+1)3kT\chi_m = \dfrac{N_{A}\mathscr{g}_e^2\mu_0\mu_B^2S(S+1)}{3kT}

where μ0\mu_0 is the vacuum permeability.

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