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(a) Data on a single crystal of give al 294.53 K. Identify the effective number of unpaired electrons in this compound and compare your result with the theoretical value. (b) Data on a single crystal of give at 298 K. Identify the effective number of unpaired electrons in this compound and compare your result with the theoretical value.
Solutions
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The magnetic susceptibility being proportional to is a result of the contribution of the thermal averaging of the permanent magnetic moments in the presence of an applied magnetic field. Thus, the spin contribution to the molar magnetic susceptibility is
where is the vacuum permeability.
(a)
Here, find the number of unpaired electrons:
We have the formula:
The values are:
is the number of unpaired electrons
is the molar susceptibility
is the Avogadro's constant
=2.0023
is the Boltzmann constant
is the spin
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