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(a) Determine the radius of the smallest cation that can have (i) sixfold and (ii) eightfold coordination with the ion (radius 181 pm). (b) Determine the radius of the smallest anion that can have (i) sixfold and (ii) eightfold coordination with the ion (radius 149 pm).
Solution
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(a) The deviation of a structure from that expected on the basis of this rule is often taken to be an indication of a shift from ionic towards covalent bonding. A major source of unreliability, though, is the arbitrariness of ionic radii and their variation with coordination number.
The radius-ratio rule is derived by considering the geometrical problem of packing the maximum number of hard spheres of one radius around a hard sphere of a different radius.
Thus,
Radius-ratio,
=
where, is the radius of the smaller ions in the crystal and that of the larger ions.
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