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A distillation column is being used to separate methanol and water at atmospheric pressure. The column temperature varies from approximately at the top to at the bottom. Liquid enters the top of the column and flows down to the bottom; vapor is generated in a reboiler at the bottom of the column, flows upward, and leaves at the top. The molar flow rate of vapor up the column may be assumed to be constant from top to bottom. The vapor velocity is kept below 5.0 ft/s to keep the vapor from entraining liquid (suspending and carrying away liquid droplets). a) Where in the column is the greatest risk of liquid entrainment? Explain your answer. b) Assuming that the liquid flowing down the column and the column internals (equipment inside the column) occupy a negligible fraction of the column cross-sectional area, estimate the minimum column diameter if the vapor flow rate is 25.0 lb-mole/min. c) Suppose the column is constructed with a diameter 10% greater than that determined in Part (b). What are the vapor velocities at the top and bottom of the column if the vapor molar flow rate in both locations is 25.0 lb-mole/min? How much can the vapor molar flow rate be increased without causing liquid entrainment? d) There is a need to increase process throughput, which would require the vapor molar flow rate to be doubled. It has been suggested that increasing the pressure in the column would allow that to be done without risking excessive liquid entrainment. Again applying a vapor velocity limit of 5 ft/s, what would the new pressure be?
Solution
VerifiedWhen methanol needs to be separated from water, a distillation column is used. This is an instrument in which the temperature varies, so that the top is at 65°C, while the bottom is at 100°C.
Liquid starts from the top and makes its way to the bottom, where a reboiler is placed to generate vapor. This vapor, because of its lightness, wants to leave the column, which it does after it flows up to the top. (Note: The vapor velocity is kept below 5.0 ft/s, and the molar flow rate is constant for the entire length of the column.)
In this subtask, we have to determine where the highest risk of liquid entrainment will be (i.e. the possibility for droplets to be carried away).
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