Question

(a) For 18O2,ΔG^{18} O_{2}, \Delta \overline{G} values for the transitions v=10,20,v=1 \leftarrow 0, 2 \leftarrow 0, and 303 \leftarrow 0 are, respectively, 1556.22, 3088.28, and 4596.21 cm1.4596.21\ \mathrm{cm}^{-1}. Calculate v\overline{v} and xe.x_{e}. Assume yey_{e} to be zero. (b) For 14N2,ΔG^{14} N_{2}, \Delta \overline{G} values for the transitions v=10,20,v=1 \leftarrow 0, 2 \leftarrow 0, and 303 \leftarrow 0 are, respectively, 2345.15, 4661.40, and 6983.73 cm1.6983.73\ \mathrm{cm}^{-1}. Calculate v\overline{v} and xe.x_{e}. Assume yey_{e} to be zero.

Solution

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(a)

In this excercise we have values of ΔG\Delta \mathrm{G} for the transitions v=10v=1 \leftarrow 0, v=20v=2 \leftarrow 0 and v=30v=3 \leftarrow 0

They are:

1556.22 cm1\mathrm{cm}^{-1}, 3088.28 cm1\mathrm{cm}^{-1} and 4596.18 cm1\mathrm{cm}^{-1}

We have to calculate v\overline{v} and xex_{\mathrm{e}}

In case of:

ΔG(v=10)=v2vxe=1556.22cm1\begin{align*} \Delta \mathrm{G}(v=1 \leftarrow 0)&=\overline{v}-2 \overline{v} x_{e}\\ &=1556.22 \mathrm{cm}^{-1}\\ \end{align*}

In case of:

ΔG(v=20)=2v6vxe=3088.28cm1\begin{align*} \Delta G(v=2 \leftarrow 0)&=2 \overline{v}-6 \overline{v} x_{e}\\ &=3088.28 \mathrm{cm}^{-1}\\ \end{align*}

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