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A hydrogen atom initially at rest in the n = 3 state decays to the ground state with the emission of a photon. (a) Calculate the wavelength of the emitted photon. (b) Estimate the recoil momentum of the atom and the kinetic energy of the recoiling atom. Where does this energy come from?

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1 Concepts and Principles

Bohr Model\textbf{Bohr Model}: Bohr postulated that:

  1. Electrons occupy only certain nonradiating, stable, circular orbits selected by quantization of the angular momentum LL.

L=mvr=nh2π=n,for integer n\begin{gather*} L=mvr=\dfrac{nh}{2\pi}=n\hbar,\quad \text{for integer }n \end{gather*}

  1. Radiation of frequency ff (wavelength λ\lambda) occurs when the electron jumps from an allowed orbit EiE_i to one of lower energy EfE_f. ff (or λ\lambda) is given by the frequency condition

E=hf=hcλ=EiEf\begin{gather*} E=hf=h\dfrac{c}{\lambda}=E_i-E_f\tag{1} \end{gather*}

The quantization of the orbit radii lead to energy quantization. The allowed energy levels are

En=(13.6  eV)Z2n2\begin{gather*} E_n=-\dfrac{(13.6\;\mathrm{eV})Z^2}{n^2} \tag{2} \end{gather*}

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