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Consider two neighbouring lakes in an isolated region of Ontario. One lake is on limestone (calcium carbonate) while the other is lined with granite. Both receive the same amount of acid precipitation, (a) Explain why the limestone lake has a higher pH than the granite lake. (b) Which lake is likely to have a healthier aquatic ecosystem? Explain your answer.

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a. Lime stone is calcium carbonate, this in the presence of acid from acid precipitation reacts to form calcium sulfate, water and carbon dioxide, according to the equation:

CaCO3(s)+H2SO4(aq)CaSO4(aq)+H2O(l)+CO2(g)\mathrm{CaCO_{3(s)} + H_2SO_{4(aq)} \longrightarrow CaSO_{4(aq)}+ H_2O_{(l)}+CO_{2(g)} }

The acid is neutralized and hence the pH of this lake is maintained. In the case of granite layered lake, this does not happen and the acid in acid precipitation only decreases the pH of the water of this lake.

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