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Continuing with the situation in the previous problem, the number of molecules in the right and left halves of a room containing molecules can be written as . For large, we expect the number of molecules in the two halves to be nearly equal so . (a) Show that the probability of a fractional discrepancy of more molecules on the right than on the left is given by
where is a constant that does not depend on . [Hint: You will need to use Stirling's approximation, , and the relation , valid for . Begin by writing and take the In of both sides.] (b) For a room containing molecules, what is the ratio (c) What values of are likely to actually occur in a room?
Solution
VerifiedThe number of particles inside the left and right halves can be defined as:
It's necessary to write the probability in the following form where the constant C doesn't depend on :
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