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Question

In one model of a solid, the material is assumed to consist of a regular array of atoms in which each atom has a fixed equilibrium position and is connected by springs to its neighbors. Each atom can vibrate in the x,yx, y, and zz directions. The total energy of an atom in this model is

E=12mvx2+12mvy2+12mvz2+12kx2+12ky2+kz2E=\frac{1}{2} m v_x^2+\frac{1}{2} m v_y^2+\frac{1}{2} m v_z^2+\frac{1}{2} k x^2+\frac{1}{2} k y^2+k z^2

What is the average energy of an atom in the solid when the temperature is TT ? What is the total energy of 1 mol1 \mathrm{~mol} of such a solid?

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Conceptual answer.

From the equipartition theorem we know two important facts for a system in equilibrium:

  • By each degree of freedom the average energy is 12kT\frac{1}{2}kT per molecule.
  • The total energy is 12RT\frac{1}{2}RT per mole by each degree of freedom.

Thus, since in this model the total energy of the solid atom depends on vxv_x,vyv_y,vzv_z,xx,yy, and zz, the system has six degrees of freedom.

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