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Question

In the gas phase, phosphorus pentachloride exists as separate molecules. In the solid phase, however, the compound is composed of alternating PC4+ and PCl6- ions. What change(s) in molecular shape occur(s) as PCI5 solidifies? How does the Cl-P-Cl angle change?

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Answered 11 months ago
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Single electron group can be:

  • single bond
  • double bond
  • triple bond
  • lone pair
  • lone electron

Electron group arrangement\textbf{Electron group arrangement} - bonding and nonbonding groups Molecule shape\textbf{Molecule shape} - bonding groups only

AXm{_m}En{_n} classification: A - central atom X - surrounding atom E - nonbonding group

The bond angle depends on the number of lone electron pairs around central atoms, because of the repulsions they cause.

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