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Question

NH3\mathrm{NH}_3 in water reacts to form NH4+\mathrm{NH}_4{ }^{+}in the equilibrium reaction:

NH3+H2ONH4++OH\mathrm{NH}_3+\mathrm{H}_2 \mathrm{O} \rightleftharpoons \mathrm{NH}_4^{+}+\mathrm{OH}^{-}

(a) Is NH3\mathrm{NH}_3 a strong or weak base?

(b) Explain why the pH\mathrm{pH} of a NH3\mathrm{NH}_3 solution is lower than that of a NaOH\mathrm{NaOH} solution:

Solution

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Consider the dissociation of ammonia (NH3_3) in water:

NH3+H2ONH4 ++OH\mathrm{NH_3 + H_2O \leftrightarrows NH_4~^{+} + OH^-}

According to this reaction and the explanation of strong acids/bases and weak acids/bases, answer the following questions:

(a) Is ammonia a weak or strong base?

(b) Why is the pH of ammonia solution lower than the pH of sodium hydroxide solution?

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