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Question

One drop of 1 M OH1~M\mathrm{~OH}^{-}ion is added to a 1 M1~M solution of HNO2\mathrm{HNO}_2. What will be the effect of this addition on the equilibrium concentration of the following?

HNO2(aq)H+(aq)+NO2(aq)\mathrm{HNO}_2(a q) \rightleftharpoons \mathrm{H}^{+}(a q)+\mathrm{NO}_2^{-}(a q)

(a) [OH]\left[\mathrm{OH}^{-}\right]
(b) [H+]\left[\mathrm{H}^{+}\right]
(c) [NO2]\left[\mathrm{NO}_2^{-}\right]
(d) [HNO2]\left[\mathrm{HNO}_2\right]

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In this task, we need to explain influence of the addition of OH^- on the equilibrium concentrations.

The equilibrium position\textbf{equilibrium position} can be affected by changing the concentration, pressure and temperature\textbf{concentration, pressure and temperature}. If one of the conditions under which the system is in a state of chemical equilibrium changes, then the equilibrium shift will be in the direction of that reaction which tends to oppose that change and to establish the previous conditions. This legality is known as the Le Chatelier’s principle\textbf{Le Chatelier's principle}.

As the concentration\textbf{concentration} of reactants\textbf{reactants} increases\textbf{increases} or the product\textbf{product} is removed \textbf{removed }from the reaction mixture, equilibrium shifts in the direction of product formation\textbf{product formation}. An equilibrium shift in the direction of the reactants\textbf{direction of the reactants} in a reaction mixture is achieved by the opposite action, ie by reducing the concentration of reactants\textbf{reducing the concentration of reactants} or by increasing the concentration of the product\textbf{increasing the concentration of the product}.

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