Question

Orbital energies in single-electron atoms or ions, such as He+\mathrm{He}^{+}, can be described with an equation similar to the Balmer-Rydberg equation:

1λ=Z2R[1m21n2]\frac{1}{\lambda}=Z^2 R_{\infty}\left[\frac{1}{m^2}-\frac{1}{n^2}\right]

where ZZ is the atomic number. What wavelength of light in nm is emitted when the electron in He+\mathrm{He}^{+}falls from n=3n=3 to n=2n=2 ?

Solution

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1λ=Z2Rc[1m21n2]\begin{align*} &\frac{1}{\lambda} = \text{Z}^{2} \cdot \text{R}_\infty \cdot \text{c} \cdot [\frac{1}{m^2} - \frac{1}{n^2}]& \end{align*}

λ\lambda - wavelength

R\text{R}_\infty - Rydberg constant equal to 1.097102 nm11.097 \cdot 10^{-2}\ \text{nm}^{-1}

c - speed of light, value is 3.001083.00 \cdot 10^{8} m/s:

Z - Atomic number

m, n - $\text{m and n represent integers with n >> m}$.

This is the Balmer-Ridberg equation\text{\underline{\text{This is the Balmer-Ridberg equation}}}

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