Related questions with answers

A 10-m3 storage tank contains methane at low temperature. The pressure inside is 700 kPa, and the tank contains 25% liquid and 75% vapor on a volume basis. The tank warms very slowly because heat is transferred from the ambient air.a. What is the temperature of the methane when the pressure reaches 10 MPa?b. Calculate the heat transferred in the process using the generalized charts.c. Repeat parts (a) and (b) using the methane tables, Table. Discuss the differences in the results.TABLE B.7 Thermodynamic Properties of Methane TABLE Saturated Methane Specific Volume, m3/kgInternal Energy, kJ/kgTemp. (K)P (kPa)vfvf gvgufuf gug90.711.70.0022153.979413.98163−358.10496.59138.499519.80.0022432.448452.45069−343.79488.62144.8310034.40.0022781.476571.47885−326.90478.96152.0610556.40.0023150.937800.94012−309.79468.89159.1111088.20.0023530.622080.62443−292.50458.41165.91111.7101.30.0023670.547600.54997−286.74454.85168.10115132.30.0023950.428000.43040−275.05447.48172.42120191.60.0024390.303670.30610−257.45436.02178.57125269.00.0024860.221080.22357−239.66423.97184.32130367.60.0025370.164480.16701−221.65411.25189.60135490.70.0025920.124580.12717−203.40397.77194.37140641.60.0026530.095750.09841−184.86383.42198.56145823.70.0027190.074450.07717−165.97368.06202.091501040.50.0027940.058390.06118−146.65351.53204.881551295.60.0028770.046050.04892−126.82333.61206.791601592.80.0029740.036380.03936−106.35314.01207.661651935.90.0030860.028680.03177−85.06292.30207.241702329.30.0032220.022410.02563−62.67267.81205.141752777.60.0033930.017180.02058−38.75239.47200.721803286.40.0036230.012660.01629−12.43205.16192.731853863.20.0039770.008460.0124318.47159.49177.961904520.50.0049680.003000.0079769.1067.01136.11190.64599.20.00614800.00615101.460101.46 Enthalpy, kJ/kgEntropy, kJ/kg-K Temp. (K)P (kPa)hfhf ghgsfsf gsg90.711.7−358.07543.12185.054.22645.989110.21559519.8−343.75537.18193.434.38055.654510.035010034.4−326.83529.77202.944.55385.29779.851410556.4−309.66521.82212.164.72084.96979.690511088.2−292.29513.29221.004.88174.66639.5480111.7101.3−286.50510.33223.834.93364.57069.5042115132.3−274.74504.12229.385.03684.38369.4205120191.6−256.98494.20237.235.18674.11849.3051125269.0−238.99483.44244.455.33213.86759.1996130367.6−220.72471.72251.005.47343.62869.1020135490.7−202.13458.90256.775.61133.39939.0106140641.6−183.16444.85261.695.74643.17758.9239145823.7−163.73429.38265.665.87942.96138.84061501040.5−143.74412.29268.546.01082.74868.75941551295.6−123.09393.27270.186.14152.53728.67871601592.8−101.61371.96270.356.27242.32488.59711651935.9−79.08347.82268.746.40462.10808.51261702329.3−55.17320.02264.856.53991.88248.42241752777.6−29.33287.20257.876.68111.64118.32231803286.4−0.53246.77246.256.83331.37108.20431853863.233.83192.16226.007.00951.03878.04831904520.591.5680.58172.147.30150.42417.7256190.64599.2129.740129.747.499907.4999 TABLE Superheated Methane Temp.vuhsvuhs(K)(m3/kg)(kJ/kg)(kJ/kg)(kJ/kg-K)(m3/kg)(kJ/kg)(kJ/kg)(kJ/kg-K) 100 kPa (111.50K)200 kPa (120.61 K)Sat.0.55665167.90223.569.50840.29422179.30238.149.29181250.63126190.21253.339.76060.30695186.80248.199.37361500.76586230.18306.7710.15040.37700227.91303.319.77591750.89840269.72359.5610.47590.44486268.05357.0210.10712001.02994309.20412.1910.75700.51165307.88410.2110.39122251.16092348.90464.9911.00580.57786347.81463.3810.64172501.29154389.12518.2711.23030.64370388.19516.9310.86742751.42193430.17572.3611.43650.70931429.36571.2211.07433001.55215472.36627.5811.62860.77475471.65626.6011.26703251.68225516.00684.2311.81000.84008515.37683.3811.44883501.81226561.34742.5711.98290.90530560.77741.8311.62203751.94220608.58802.8012.14910.97046608.07802.1611.78854002.07209657.89865.1012.30991.03557657.41864.5311.94954252.20193709.36929.5512.46611.10062708.92929.0512.1059 400 kPa (131.42 K)600 kPa (138.72 K)Sat.0.15427191.01252.729.07540.10496197.54260.518.94581500.18233223.16296.099.38430.11717218.08288.389.13901750.21799264.61351.819.72800.14227261.03346.399.49702000.25246305.19406.1810.01850.16603302.44402.069.79442250.28631345.61460.1310.27260.18911343.37456.8410.05252500.31978386.32514.2310.50070.21180384.44511.5210.28302750.35301427.74568.9410.70920.23424426.11566.6610.49313000.38606470.23624.6510.90310.25650468.80622.6910.68823250.41899514.10681.6911.08570.27863512.82680.0010.87163500.45183559.63740.3611.25950.30067558.48738.8811.04613750.48460607.03800.8711.42650.32264605.99799.5711.21364000.51731656.47863.3911.58790.34456655.52862.2511.37544250.54997708.05928.0411.74460.36643707.18927.0411.53244500.58260761.85994.8911.89740.38826761.05994.0011.68554750.61520817.891063.9712.04680.41006817.151063.1811.83515000.64778876.181135.2912.19310.43184875.481134.5911.98165250.68033936.671208.8112.33660.45360936.031208.1812.1252 800 kPa (144.40 K)1000 kPa (149.13 K)Sat.0.07941201.70265.238.85050.06367204.45268.128.77351500.08434212.53280.008.95090.06434206.28270.628.79021750.10433257.30340.769.32600.08149253.38334.879.18712000.12278299.62397.859.63100.09681296.73393.539.50062250.14050341.10453.509.89320.11132338.79450.119.76722500.15781382.53508.7810.12620.12541380.61506.0110.00282750.17485424.47564.3510.33810.13922422.82562.0410.21643000.19172467.36620.7310.53430.15285465.91618.7610.41383250.20845511.55678.3110.71860.16635510.26676.6110.59903500.22510557.33737.4110.89380.17976556.18735.9410.77483750.24167604.95798.2811.06170.19309603.91797.0010.94334000.25818654.57861.1211.22390.20636653.62859.9811.10594250.27465706.31926.0311.38130.21959705.44925.0311.26364500.29109760.24993.1111.53460.23279759.44992.2311.41724750.30749816.401062.4011.68450.24595815.661061.6111.56725000.32387874.791133.8911.83110.25909874.101133.1911.71415250.34023935.381207.5611.97490.27221934.731206.9511.85805500.35657998.141283.4512.11610.28531997.531282.8411.9992 1500 kPa (158.52 K)2000 kPa (165.86 K)Sat.0.04196207.53270.478.62150.03062207.01268.258.49751750.05078242.64318.818.91210.03504229.90299.978.68392000.06209289.13382.269.25140.04463280.91370.179.05962250.07239332.85441.449.53030.05289326.64432.439.35322500.08220375.70499.009.77300.06059370.67491.849.60362750.09171418.65556.219.99110.06796414.40550.319.82663000.10103462.27613.8210.19160.07513458.59608.8510.03033250.11022507.04672.3710.37900.08216503.80668.1210.22003500.11931553.30732.2610.55650.08909550.40728.5810.39923750.12832601.30793.7810.72630.09594598.69790.5710.57034000.13728651.24857.1610.88990.10274648.87854.3410.73494250.14619703.26922.5411.04840.10949701.08920.0610.89424500.15506757.43990.0211.20270.11620755.43987.8411.04914750.16391813.801059.6611.35320.12289811.941057.7211.20035000.17273872.371131.4611.50050.12955870.641129.7411.34805250.18152933.121205.4111.64480.13619931.511203.8811.49275500.19031996.021281.4811.78640.14281994.511280.1311.6346 4000 kPa (186.10 K)8000 kPaSat.0.01160172.96219.348.0035————2000.01763237.70308.238.46750.0041255.5888.547.20692250.02347298.52392.398.86530.00846217.30284.988.13442500.02814349.08461.639.15740.01198298.05393.928.59542750.03235396.67526.079.40310.01469357.88475.398.90643000.03631443.48588.739.62120.01705411.71548.159.15983250.04011490.62651.079.82080.01924463.52617.409.38153500.04381538.70713.9310.00710.02130515.02685.399.58313750.04742588.18777.8610.18350.02328567.12753.349.77064000.05097639.34843.2410.35230.02520620.38821.959.94774250.05448692.38910.3110.51490.02707675.14891.7110.11694500.05795747.43979.2310.67250.02891731.63962.9210.27964750.06139804.551050.1210.82580.03072789.991035.7510.43725000.06481863.781123.0110.97530.03251850.281110.3410.59025250.06820925.111197.9311.12150.03428912.541186.7410.73935500.07158988.531274.8611.26460.03603976.771264.9910.88495750.074951053.981353.7711.40490.037761042.961345.0711.0272

Question

Sandy's Rock and Gravel Company wants to shift a mountain of gravel, estimated at about 20000 tons, from one side of their yard to the other. For this they intend to use a power shovel to fill a hopper, which in turn feeds a belt conveyor. The latter then transports the gravel to the new location. The shovel scoops up large amounts of gravel at first; however, as the gravel supply decreases, the handling capacity of the shovel also decreases because of the increased time required to move away from the hopper for a load and then return and dump. Roughly, then, we may estimate that the shovel's gravel handling rate is proportional to the size of the pile still to be moved, its initial rate being 10 ton/min. The conveyor, on the other hand, transports the gravel at a uniform 5 ton/min. At first the shovel will work faster than the conveyor, then slower. Hence, the storage bin will first accumulate material, then empty. (a) What will be the largest amount of gravel in the bin? (b) When will this occur? (c) When will the rates of bin input and output be equal? (d) When will the bin become empty?

Solution

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The initial gravel handling rate of the shovel is 1010 tonmin\mathrm{\dfrac{ton}{min}}. It is also mentioned that the shovel’s gravel handling rate is directly proportional to the size of the pile still to be moved. So it shows that the removal of the sand using a shovel can be compared to the first order reaction.

The conveyor, on the other hand, works at the uniform rate of 55 tonmin\mathrm{\dfrac{ton}{min}}. This shows that the working of the conveyor is independent of the amount of sand in the hopper. So it can be considered as the zero order reaction

We can represent above system as a

A1storderR0orderS\begin{align*} A \xrightarrow{1st order}R \xrightarrow{0-order}S\\ \end{align*}

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