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The compressibility κ\kappa of a substance is defined as the fractional change in volume of that substance for a given change in pressure:

κ=1VdVdP\kappa=-\frac{1}{V} \frac{d V}{d P}

(a) Explain why the negative sign in this expression ensures κ\kappa is always positive. (b) Show that if an ideal gas is compressed isothermally, its compressibility is given by κ1=1/P\kappa_{1}=1 / P. (c) Show that if an ideal gas is compressed adiabatically, its compressibility is given by κ2=1/(γP).\kappa_{2}=1 /(\gamma P) . Determine values for (d) κ1\kappa_{1} and (e) κ2\kappa_{2} for a monatomic ideal gas at a pressure of 2.00 atm.

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The compressibility k of a substance is defined as:

k=1VdVdPk=-\dfrac{1}{V}\cdot \dfrac{dV}{dP}

A)\textbf{A)} If the pressure increases, the volume will decreases, and otherwise. So the - sign will ensure that compressibility of a substance always stays positive.

 B)\textbf{ B)} Ifan ideal gas is compressed isothermally, its compressibility is given by:

k1=1VdVdP=1VddP(nRTP)=nRTVddP(1P)=nRTVP2=PP2=1P\begin{align*} k_1&=-\dfrac{1}{V}\cdot \dfrac{dV}{dP}=-\dfrac{1}{V}\cdot \dfrac{d}{dP}\left(\dfrac{nRT}{P}\right)=-\dfrac{nRT}{V} \dfrac{d}{dP}\left(\dfrac{1}{P}\right)\\\\ &=\dfrac{nRT}{VP^2} =\dfrac{P}{P^2}\\\\ &=\boxed{\dfrac{1}{P}}\\ \end{align*}

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