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Consider the dimerization 2AA22 \mathrm { A } \rightleftarrows \mathrm { A } _ { 2 } , with forward rate constant kak_a and backward rate constant kak'_a. (a) Derive the following expression for the relaxation time in terms of the total concentration of protein, [A]tot=[A]+2[A2][A]_{tot} = [A] + 2[A_2]: 0.20 mmol dm3dm^{−3}. Calculate the rate constants for the forward and reverse steps. 1τ2=ka2+8kaka[A]tot\frac { 1 } { \tau ^ { 2 } } = k _ { \mathrm { a } } ^ { \prime 2 } + 8 k _ { \mathrm { a } } k _ { \mathrm { a } } ^ { \prime } [ \mathrm { A } ] _ { \mathrm { tot } }. (b) Describe the computational procedures that lead to the determination of the rate constants kak_a and kak'_a from measurements of τ\tau for different values of [A]tot[ \mathrm { A } ] _ { \mathrm { tot } }. (c) Use the data provided below and the procedure you outlined in part (b) to calculate the rate constants kak_a and kak'_a, and the equilibrium constant K for formation of hydrogen-bonded dimers of 2-pyridone:

 [P]/(moldm3)0.5000.3520.2510.1510.101 τ/ns2.32.73.34.05.3\begin{matrix} \ {[P]/(mol dm^{−3})} & \text{0.500} & \text{0.352} & \text{0.251} & \text{0.151} & \text{0.101}\\ \ {\tau / \mathrm { ns }} & \text{2.3} & \text{2.7} & \text{3.3} & \text{4.0} & \text{5.3}\\ \end{matrix}

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The Latin root -jec-means "thro w." This root is found in many scientific words, such as conjecture, which means "to guess by 'throwing' facts or inferences together."
Choose the letter of the best definition for the given word below. "deject ": a. to "throw" forward b. to "throw" into c. to "throw" out of d. object designed to be "thrown" or shot e. path along which an object is "thrown" f. "thrown" away; hopeless g. state of being "thrown" down; depression h. "throw" back at

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Deject is a word that describes the feeling of being "thrown" down depression. This is connected with a person who is at the bottom of their mental health. It may happen to anyone who is experiencing loss, sadness, or disappointment.

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